Main Article Content
Abstract
Purpose of Study: The review article explores the kinetic and mechanistic aspects of ruthenium(III) chloride catalysis in the oxidation of organic and inorganic substrates using cerium(IV) as the oxidizing agent in an aqueous acid medium. The reactions have been classified based on the type of metal ion catalyst used. The article highlights that the nature of the mechanism of catalytic oxidation of alcohols by Ce(IV) depends on the specific metal ion catalyst used and the nature of the acidic medium employed.
Methodology: The article sheds light on the purpose and scope of catalytic oxidation of alcohols by Ce(IV). The oxidation of alcohols is an essential reaction in organic chemistry and has numerous applications in the synthesis of various organic compounds. The use of Ce(IV) as an oxidizing agent in the presence of a suitable catalyst can provide an efficient and selective method for the oxidation of alcohols.
Principal Findings: The article discusses the role of ruthenium(III) chloride as a catalyst in the oxidation of alcohols in the presence of Ce(IV) and provides insights into the reaction mechanism. The review also highlights the importance of the nature of the acidic medium used in the reaction and its effect on the reaction kinetics and mechanism.
Implications: Overall, the review article provides a comprehensive overview of the use of ruthenium(III) chloride as a catalyst in the oxidation of alcohols using Ce(IV) as an oxidizing agent in an aqueous acid medium. The insights provided in this article can be valuable for researchers working in the area of organic and inorganic chemistry.
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References
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References
Ardon, M.J. Chem. Soc. 1811 (1957).https://doi.org/10.1039/jr9570001811
Benson, D.; "Mechanism by oxidation by metal ions" Elsevier Sciencific Publishing company, Amesterdam (1976).
Blaustein, B.D.; Gryder, J.W. J. Am. Chem. Soc. 79, 540 (1957).https://doi.org/10.1021/ja01560a012
Bugaenko, L.T.; Huaf, kuan Lin, Russ. J. Inorg. Chem. 8, 299 (1963).
Cady, H.H.; Connik, R.F. J. Am. Chem. Soc. 80, 2646 (1958).https://doi.org/10.1021/ja01544a012
Conant, J.B.; Aston, J.G. J. Am. Chem. Soc. 50, 2783 (1928).https://doi.org/10.1021/ja01397a033
Connik, R.F.; Fine, D.A. J. Am. Chem. Soc. 83, 3416 (1961); ibid. 82, 4187 (1960).
https://doi.org/10.1021/ja01477a014
Dorfman, M.K.; Gryder, J.W. Inorg. Chem.1, 799 (1962).https://doi.org/10.1021/ic50004a017
Drummond, A.Y.; Waters, W.A. J. Chem. Soc. 440 (1953), Ibid, 497 (1955).
https://doi.org/10.1039/jr9550000497
Duke, F.R.; Bremer, R.F. J. Am. Chem. Soc. 73, 5179 (1951).https://doi.org/10.1021/ja01155a051
Duke, F.R.; Florist, A.A. J. Am. Chem. Soc. 71, 2790 (1949).https://doi.org/10.1021/ja01176a056
Duke, F.R.; Smith, G.F. Ind. Eng. Chem. Anal. Ed. 12, 201 (1940).
https://doi.org/10.1021/ac50144a008
Griffith, W.P. "The Chemistry of the Rare Platinum Metals", Interscience, New York, p. 141, (1967).
Guilbailt, G. G.; Mac Curdy (Jr) W.H. Phys. Chem. 67, 283 (1963).
Halpern, J.; Jones, B.H.; Kemp, A.L.W. J. Am. Chem. Soc. 83, 4097 (1961).
https://doi.org/10.1021/ja01480a036
Hardwick, T.J.; Robertson, E. Can. J. Chem., 29, 828 (1951).https://doi.org/10.1139/v51-095
Hargreaves, G.; Suteliffe, L.H. Trans. Faraday. Soc., 51, 1105 (1955).https://doi.org/10.1039/tf9555101105
Harrod, J.F.; Coccone, S.; Halpern, J. Can. J. Chem. 39, 1372. (1961).https://doi.org/10.1139/v61-171
Ho, T. L. Synthesis, 347 (1973).https://doi.org/10.1055/s-1973-22210
Ho, T.L. "Organic synthesis with metal compounds "Ed. Mijs, W. I. and De Jonge, C. R. H. Plenum Publishing Corp, P. 569 (1986).
Jones, E.G.; Soper, P.G. J. Chem. Soc., 802 (1935).https://doi.org/10.1039/jr9350000802
Litller, J. S., J.; Chem. Soc. 4135 (1959).
Litller, J.S.; Waters, W.A. J. Chem. Soc. 2757 (1960)
Mac Auley; Brubaker (Jr.) C. H. J. Chem. Soc. (A) 960 (1996).
Marroco, M.; Brilmyer, G. J. Org. Chem. 48, 1487 (1983).https://doi.org/10.1021/jo00157a021
McCurdy, W. H. (Jr); Guilbailt, G. G. J. Phys. Chem., Soc., 64, 1825 (1960).
https://doi.org/10.1021/j100841a006
Meyers, R.J.; Jacoby, R.Z. J. Inorg. Chem. 27, 359 (1901).https://doi.org/10.1002/zaac.19010270131
Mino, G.; Kaizarman, S.; Rasmussen, G. J. Am. Chem. Soc., 81, 1494 (1959).
https://doi.org/10.1021/ja01515a053
Moore, R.L.; Anderson, R.C. J. Am. Chem. Soc. 67, 167 (1945).https://doi.org/10.1021/ja01218a005
Muhammad, S.S.; Rao, K.V., Bull. Chem. Soc. Japan. 36. 943, (1963).https://doi.org/10.1246/bcsj.36.943
Offner, H.G.; Skoog, D.A. Anal. Chem. 37, 1018 (1965).https://doi.org/10.1021/ac60227a018
Ogata, Y.; Tabusi, I. Kagaku no Ryoiki 12, 489 (1958) Chem.; (Prague) 10, 1022 (1958); Chem., Abstr. 54, 1250 g (1960).
Paquatte, D.; Zador, M. Can. J. Chem. 46, 3507 (1968).https://doi.org/10.1139/v68-581
Prakash, A.; Mehrotra, R.N.; Kapoor, R.C., J. Chem. Soc. Dalton Trans. 3781 (1972).
Richardson, W.H. in "Oxidation in Organic Chemistry", Wiberg, K.B. Ed. ., Part A, Academic Press, New York, chap. IV (1965).
Sankhala, P.S.; Mehrotra, R.N. Inorg. Nuclear Chem. 35, 891 (1973).https://doi.org/10.1016/0022-1902(73)80459-2
Sankhala, P.S.; Mehrotra, R.N. J. Inorg. Nuclear Chem. 34, 3781 (1972).https://doi.org/10.1016/0022-1902(72)80025-3
Sant, P.G.; Bhaleand, V.M.; Bhagwat, W.V. Ind. J. Chem. 4, 3781 (1972).
Shankhla, P.S.; Mehrotra, R.N. Indian J. Chem. 14 A 663 (1976). Ibid, 13, 904 (1975); J. Inorg. Nucl. Chem. 5, 891 (1973).
Singh, H.S. "Organic synthesis by oxidation with metal compounds", Ed. Mijs, W. J.; de jonge, C.R.H. Plenum Publishing Corp., p. 633 (1987).
Singh, H.S.; Singh, B.; Gupta, A., Proc. Natl. Acad., Sci. 68(A), IV (1998).
Singh, J.P.; Sirohi J.S., Proceeding at 67th Indian Science Congress (1990).
Singh, M.P.; Ghosh, S. Zeit physic Chem. 207, 198 (1957).https://doi.org/10.1515/zpch-1957-20723
Singh, M.P.; Singh, H.S.; Verma, M.K. J. Phys. Chem. 84, 256 (1980).
https://doi.org/10.1021/j100440a006
Smith, G.F. "Cerate Oxidimetary", G. Frederick Smith Chemical Co. Columbus Ohio (1942).
Song, W. Y.; Li, H. B.; and Hong, M.; Acta Physico chemical Sinika 20, 8. 801 (2004).
https://doi.org/10.3866/PKU.WHXB20040804
Song, W. Yu; Zhao, R.H.; Jiang, Q. M.; WuliHauxueXuebao 21 (8), 929 (2005).
Song, W.; Zhao, R.; Li, Y.; Xu, J. Chem. J. Internet 7, 11, 77 (2007).
Subramanian, N.V.; Balsubramanian, T.R., Ind. J. Chem. 8, 305 (1970).
Syper, L.; Tetrahedron Lett. 4493 (1966).https://doi.org/10.1016/S0040-4039(00)70065-7
Tandon, P.K.; (km) Manibala; Singh, H.S.; Krishna B. Z. Phys. Chemic., Lipzig. 265, 3, 5, 609 (1984): Verma, M.K.; Tandon, P.K.; Singh, M.P. Z. Phys. Chemic, Lipzig 26, 1153 (1985).
https://doi.org/10.1515/zpch-1984-26584
Tandon, P.K.; Gayatri; Sahgal, S.; Srivastava, M.; Singh S.B. Appl. Org. Met. Chem. 21, 135 (2007).
https://doi.org/10.1002/aoc.1169
Tandon, P.K.; Krishna, B. KinetiaiKataliz, 26, 3, 607 (1985).
Tandon, P.K.; Purwar, M.; Singh, S.; Srivastava, N. J. Mol. Catal. A: Chemical, 284, 136 (2008).
https://doi.org/10.1016/j.molcata.2008.01.002
Tandon, P.K.; Sahgal, S.; Gayatri; Purwar M.; Dhusia , M. J. Mol. Catal. A. Chemical, 250, 203 (2006).
https://doi.org/10.1016/j.molcata.2005.12.045
Tandon, P.K.; Sahgal, S.; Singh, A.K.; Gayatri; Puwar, M. J. Mol. Catal. A: Chemical 232, 83 (2005).
https://doi.org/10.1016/j.molcata.2005.01.031
Tandon, P.K.; Sahgal, S.; Singh, A.K.; Kumar, S.; Dhusia, M.; J. Mol. Catal. A: Chemical, 258, 320 (2006).https://doi.org/10.1016/j.molcata.2006.05.060
Tandon, P.K.; Singh, A.K.; Baboo, R.; Dwivedi, P.B. Trans. Metal Chem. 29, 663 (2004).
https://doi.org/10.1007/s11243-004-5162-9
Tandon, P.K.; Singh, A.K.; Sahgal, S.; Kumar, S. J. Mol. Catal. A: Chemical, 282, 136 (2008).
https://doi.org/10.1016/j.molcata.2007.12.001
Trahanovsky, W.S.; Young, L. B., J. Chem. Soc. 5777 (1965).
Vishavandham, C.S.; Rao, G. G. Current Science, 12, 327 (1943).
Wiberg, K.B. "Oxidation in organic chemistry" part A, p. 185, Acadmic press, New York (1965).
Wiberg, K.B. "Oxidation in organic chemistry" part A, p. 406, Acadmic press, New York (1965).
Wiberg, K.B. "Oxidation in Organic chemistry" Part A, P.278, Academic press, New York (1965).
Wibrg, K.B.; Ford, P.C. J. Am. Chem. Soc. 91, 124 (1969).https://doi.org/10.1021/ja01029a026
Wordsworth, E.; Duke, F.R.; Goetz, C.A. Anal. Chem. 29, 1828 (1957). https://doi.org/10.1021/ac60132a046
Young, L.B.; Trahanovsky, W.S. J. Am. Chem. Soc. 91, 5060 (1969). https://doi.org/10.1021/ja01046a021