Main Article Content
Abstract
Purpose of study: The main objective of this research is to extract zinc from Electric Arc Furnace Dust (EAFD) using a hydrometallurgical process with sulfuric acid as the leaching agent. Additionally, the study aims to analyze the mineral and chemical composition of the leachate using X-ray diffraction and scanning electron microscopy.
Methodology: Four leaching parameters, namely acid concentration, temperature, reaction time, and solid-to-liquid ratio, were investigated. The chemical composition of EAFD was characterized using X-ray diffraction (XRD). Additionally, the mineral and chemical composition of the leachate's main functional groups were analyzed using XRD and scanning electron microscopy (SEM).
Main Findings: Optimal leaching conditions for achieving maximum zinc recovery from EAFD included 1N H2SO4 concentration, a temperature of 25°C, a reaction time of 2 hours at a constant speed of 1500 rpm, and a solid-to-liquid ratio of 10 ml/g. Under these conditions, the zinc recovery percentage reached 85%. Furthermore, the chemical composition of the EAFD, as determined by X-ray diffraction (XRD), revealed the following percentages: 30.7% Zn, 14.4% Fe, 13.3% Ca, and 4.2% Pb.
Implications: The findings of this study contribute to the advancement of sustainable and efficient processes for recovering valuable metals from industrial waste. By promoting resource conservation and environmental protection, these findings support the development of more environmentally friendly practices in the industry.
Keywords
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References
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- Habashi F. (2018). Pyro- versus hydrometallurgy or dry versus wet methods, Juniper online journal material science, 3(4), 1-5.
- Halli P., Hamuyuni J., Leikola M. and Lundström M. (2018). Developing a sustainable solution for recycling electric arc furnace dust via organic acid leaching, Minerals Engineering, 24(2), 1-9.https://doi.org/10.1016/j.mineng.2018.05.011
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- https://doi.org/10.6000/1927-5129.2016.12.50
- Havlik T., Turzakovaa M., Stopicb S. and Friedrich B. (2005). Atmospheric leaching of EAF dust with diluted sulphuric acid, Hydrometallurgy, 77(2), 41-50. https://doi.org/10.1016/j.hydromet.2004.10.008
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- Magdziarz A., Victor A. (2015). Briquetting of EAF dust for its utilization in metallurgical processes. Chemical and Process Engineering, 36 (2), 263-271. https://doi.org/10.1515/cpe-2015-0018
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- Ruiz O., Clemente C., Alonso M. and Alguacil J. (2007). Recycling of an electric arc furnace flue dust to obtain high grade ZnO. Journal of Hazardous Materials, 7 (1), 33-36. https://doi.org/10.1016/j.jhazmat.2006.06.079
- PMid:16876937
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- Shawabkeh R., (2010). Hydrometallurgical extraction of zinc from Jordanian electric arc furnace dust. Hydrometallurgy, 104 (1), 61-65. https://doi.org/10.1016/j.hydromet.2010.04.014
- Suetens T., Guo M., Van Acker K., Blanpain B. (2015). Formation of the ZnFe2O4 phase in an electric arc furnace off-gas treatment system, Hazardous Materials, 287, 180-187.https://doi.org/10.1016/j.jhazmat.2015.01.050, PMid:25646901
- Tsakirdis P.E., Qustadakis P., Katsiapi A., Leonardou A.S. (2010). Hydrometallurgical process for zinc recovery from electric arc furnace dust (EAFD). Part II: Downstream processing, PMid:20434263
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- https://doi.org/10.15344/2455-2372/2016/121
- Wang H., Yang L., Gao J., Zhang M. and Guo M. (2015). Novel hydrothermal method for zinc extraction and separation from zinc ferrite and electric arc furnace dust. International Journal of Minerals, Metallurgy and Materials, 23(2), 146-155. https://doi.org/10.1007/s12613-016-1221-4
- Xanthopoulos P., Agatzini-Leonardou S., Oustadakis P. and Tsakiridis P.E. (2017). Zinc recovery from purified electric arc furnace dust leach liquors by chemical precipitation, Environmental Chemical Engineering. 46 (17), 2213-3437. https://doi.org/10.1016/j.jece.2017.07.023
- Yao Y.T., Hwang S.L., Yong C.L., Seng W.C., Kin O.L. (2018). Hydrometallurgical Extraction of Zinc and Iron from Electric Arc Furnace Dust (EAFD) using Hydrochloric Acid, Journal of Physical Science, 29, 49-54.https://doi.org/10.21315/jps2018.29.s3.6
- Zhang H., Jain L., Anjun X., Yang Q., Dong Feng H. and Tian N. (2014). Carbothermic reduction of zinc and iron oxides in electric arc furnace dust, Journal of Iron and Steel Research, 21 (4), 427-432.https://doi.org/10.1016/S1006-706X(14)60066-2
References
Brunelli K. and Dabalà M. (2015).Ultrasound effects on zinc recovery from EAF dust by sulfuric acid leaching. International Journal of Minerals, Metallurgy and Materials, 22(4), 353-361.https://doi.org/10.1007/s12613-015-1080-4
Carranza F., Romero R., Mazuelos A., Iglesias N. (2016). Recovery of Zn from acid mine water and electric arc furnace dust in an integrated process, Journal of Environmental Management, 165, 175-183.https://doi.org/10.1016/j.jenvman.2015.09.025, PMid:26433358
Dutra A.J.B., PaivaP.R.P., Tavares L.M. (2006). Alkaline leaching of zinc from electric arc furnace steel dust, Minerals Engineering, 19, 478-485. https://doi.org/10.1016/j.mineng.2005.08.013
Habashi F. (2018). Pyro- versus hydrometallurgy or dry versus wet methods, Juniper online journal material science, 3(4), 1-5.
Halli P., Hamuyuni J., Leikola M. and Lundström M. (2018). Developing a sustainable solution for recycling electric arc furnace dust via organic acid leaching, Minerals Engineering, 24(2), 1-9.https://doi.org/10.1016/j.mineng.2018.05.011
Hameed Z., Shehap S. and Salaam D. (2016). Effect of acid treatment on the recovery of valuable metals from steel plant exhaust, Journal of Basic & Applied Sciences, 12(1), 323-328.
https://doi.org/10.6000/1927-5129.2016.12.50
Havlik T., Turzakovaa M., Stopicb S. and Friedrich B. (2005). Atmospheric leaching of EAF dust with diluted sulphuric acid, Hydrometallurgy, 77(2), 41-50. https://doi.org/10.1016/j.hydromet.2004.10.008
Jorge P., Buzin V., Cezar N. and Vilela C. (2016). EAF dust: An overview on the influences of physical, chemical and mineral features in its recycling and waste incorporation routes, Journal of Material Research and Technology, 6(2), 194-202. https://doi.org/10.1016/j.jmrt.2016.10.002
Khaliq A., Rhamdhani M.A., Brooks G., Masood S. (2014). Metal Extraction Processes for Electronic Waste and Existing Industrial Routes: A Review and Australian Perspective, Resources, 3, 152-179.
https://doi.org/10.3390/resources3010152
Khattab R.M., Selemanb M.M. El-Sayed, Zawrah M.F (2017). Assessment of electric arc furnace dust: Powder characterization and its sinterability as ceramic product, Ceramics International, 43, 12939- 12947.
https://doi.org/10.1016/j.ceramint.2017.06.192
Laura M., Simonyan, Anna A., Nadezhda, Demidova V. (2019) The EAF dust chemical and phase composition research techniques, Journal of material science research and technology, 8(2), 1601-1607.https://doi.org/10.1016/j.jmrt.2018.11.005
Lee H.S., Park D.S.M., Hwang Y., Jong G.H. (2020). Toward high recovery and selective leaching of zinc from electric arc furnace dust with different physicochemical properties, Environmental Engineering Research, 25(3), 335-344. https://doi.org/10.4491/eer.2019.132
Magdziarz A., Victor A. (2015). Briquetting of EAF dust for its utilization in metallurgical processes. Chemical and Process Engineering, 36 (2), 263-271. https://doi.org/10.1515/cpe-2015-0018
Oustadakis P, Tsakiridis PE, Katsiapi A, Agatzini-Leonardou S. (2010). Hydrometallurgical process for zinc recovery from electric arc furnace dust (EAFD): part I: Characterization and leaching by diluted sulphuric acid, Journal Hazardous Materials, 179, 1-3. https://doi.org/10.1016/j.jhazmat.2010.01.059, PMid:20129730
Park S.M., Yoo J.C., Ji S.W., Yang J.S., Baek K. (2015). Selective recovery of dissolved Fe, Al, Cu, and Zn in acid mine drainage based on modeling to predict precipitation pH, Environmental science and pollution research international, 22 (4), 3013-3022. https://doi.org/10.1007/s11356-014-3536-x, PMid:25231736
Ruiz O., Clemente C., Alonso M. and Alguacil J. (2007). Recycling of an electric arc furnace flue dust to obtain high grade ZnO. Journal of Hazardous Materials, 7 (1), 33-36. https://doi.org/10.1016/j.jhazmat.2006.06.079
PMid:16876937
Santos F., Brocchi P., Arau V., Souza R. ((2015)). Behavior of Zn and Fe content in electric arc furnace dust as submitted to chlorination methods. Metallurgical and Materials Transactions, 46 (4), 1729-1714.https://doi.org/10.1007/s11663-015-0347-5
Shawabkeh R., (2010). Hydrometallurgical extraction of zinc from Jordanian electric arc furnace dust. Hydrometallurgy, 104 (1), 61-65. https://doi.org/10.1016/j.hydromet.2010.04.014
Suetens T., Guo M., Van Acker K., Blanpain B. (2015). Formation of the ZnFe2O4 phase in an electric arc furnace off-gas treatment system, Hazardous Materials, 287, 180-187.https://doi.org/10.1016/j.jhazmat.2015.01.050, PMid:25646901
Tsakirdis P.E., Qustadakis P., Katsiapi A., Leonardou A.S. (2010). Hydrometallurgical process for zinc recovery from electric arc furnace dust (EAFD). Part II: Downstream processing, PMid:20434263
Varga T., Bokanyi, L. and Torok, T. (2016). Aqueous recovery of zinc from dust and slags of the iron and steel production technologies, International Journal of Metallurgical & Materials Engineering, 2, 2372-2455.
https://doi.org/10.15344/2455-2372/2016/121
Wang H., Yang L., Gao J., Zhang M. and Guo M. (2015). Novel hydrothermal method for zinc extraction and separation from zinc ferrite and electric arc furnace dust. International Journal of Minerals, Metallurgy and Materials, 23(2), 146-155. https://doi.org/10.1007/s12613-016-1221-4
Xanthopoulos P., Agatzini-Leonardou S., Oustadakis P. and Tsakiridis P.E. (2017). Zinc recovery from purified electric arc furnace dust leach liquors by chemical precipitation, Environmental Chemical Engineering. 46 (17), 2213-3437. https://doi.org/10.1016/j.jece.2017.07.023
Yao Y.T., Hwang S.L., Yong C.L., Seng W.C., Kin O.L. (2018). Hydrometallurgical Extraction of Zinc and Iron from Electric Arc Furnace Dust (EAFD) using Hydrochloric Acid, Journal of Physical Science, 29, 49-54.https://doi.org/10.21315/jps2018.29.s3.6
Zhang H., Jain L., Anjun X., Yang Q., Dong Feng H. and Tian N. (2014). Carbothermic reduction of zinc and iron oxides in electric arc furnace dust, Journal of Iron and Steel Research, 21 (4), 427-432.https://doi.org/10.1016/S1006-706X(14)60066-2