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Abstract
The liquid-liquid extraction (LLE) and supported liquid membrane (SLM) studies of reactive dyes namely Gold Yellow (GYHE-R) and Reactive Green HE 4BD (RGHE-4BD) from aqueous solution using Aliquot 336 as the carrier has been investigated. Polytetrafluoroethylene (PTFE) membrane with 0.5 μm pore size has been used after impregnated with Aliquot 336 in dichloromethane. In liquid liquid extraction the following parameters had been optimized; pH of feed, diluent, carrier , strip and dye concentration and the same parameters have been applied to supported liquid membrane (SLM) study to transport dye from aqueous solution.
The main advantages SLM study is; the extraction and stripping as single stage process and low consumption of carrier in the membrane phase compared to the solvent extraction process. The other parameters such as transport time, stirring speed and mechanism of dye transport has also studied by SLM. The percentage of transport of dye and flux rate increases with increasing time. The stability of membrane is satisfactory over 5 days.
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References
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References
G. Muthuraman, T. T. Teng, Extraction of methyl red from industrial wastewater using xylene as an extractant. Prog. Nat. Sci. 19 (2009) 1215-1220. DOI: https://doi.org/10.1016/j.pnsc.2009.04.002
S. Elumalai, G. Muthuraman. Recovery of methyl orange and Congo red from aqueous solutions using tri-octyl amine (TOA) as carrier. Process Saf. Env. Prot. 96 (2015) 177-183. DOI: https://doi.org/10.1016/j.psep.2015.05.007
S. Elumalai G. Muthuraman, M. Sathya, M. Soniya, T. T. Teng. Recovery of dye from textile effluents using phenol as an extractant. 20 (2014) 1958-1964. DOI: https://doi.org/10.1016/j.jiec.2013.09.017
N. M. Kocherginsky, Q. Yang, Big carrousel mechanism of copper removal from ammonical wastewater through supported liquid membrane. Sep. Purif. Technol, 54 (2007) 104-116. DOI: https://doi.org/10.1016/j.seppur.2006.08.019
A. Gherrou, H. Kerdjoudj, R. Molinari, E. Drioli. Removal of silver copper ions from acidic thiourea solutions with a supported liquid membranes containing D2EHPA as carrier. Sep. Purif. Technol. 28 (2002) 235-244. DOI: https://doi.org/10.1016/S1383-5866(02)00080-1
P. Dzygiel, P. Wieczorek. Stereoselective transport of amino acids and peptides through liquid membranes. Chem. Pap. 56 (2002) 24-31.
L. Chimuka, E. Cukrowska, L. Soko, K. Naicker. Supported-Liquid membrane extraction as a selective sample preparation technique in monitoring Uranium in comlex meatrix samples. J. Sep. Sci. 26 (2003) 601-605. DOI: https://doi.org/10.1002/jssc.200390082
A. Poliwoda, N. Ilczuk, P. Wieczorek. Transport mechanism of peptides through supported liquid membranes. Sep. Purif. Technol. 57 (2007) 444-449. DOI: https://doi.org/10.1016/j.seppur.2006.05.015
G. Muthuraman, K. Palanivelu. Removal of CI Reactive Yellow 125, CI Reactive Red 158 and CI Reactive Red 159 dyes from aqueous solution with a supported liquid membrane containing tri-butyl phosphate as carrier. J. Text. Inst. 97 (2006) 341-347. DOI: https://doi.org/10.1533/joti.2005.0161
F. N. Memon, S. Memon. Rapid transfer of methyl red using calix[6]arene as a carrier in a bulk liquid membrane. C. R. Chimie. 17 (2014) 577-585. DOI: https://doi.org/10.1016/j.crci.2013.09.015
S. Elumalai, G. Muthuraman. Comparative study of liquid-liquid extraction and bulk liquid membrane for rhodamine B. Inter J. Eng. Innov. Technol. 3 (2013) 387-392.
N. Hajarabeevi, I. Mohammed Bilal, D. Eswaramoorthi, K. Palanivelu. Facilitated transport of caionic dyes through a supported liquid membrane with D2EHPA as carrier. Desalination 24 (2009) 19-27. DOI: https://doi.org/10.1016/j.desal.2008.06.009
I. M. Coelhoso, M. M. Cardoso, R. M. C. Viegas, J. P. S. G. Crespo. Transport mechanisms and modelling in liquid membrane contactors, Sep. Purif. Technol. 19 (2000) 183-197. DOI: https://doi.org/10.1016/S1383-5866(00)00051-4
G. Muthuraman K. Palanivelu. Transport of textile dye in vegetable oils based supported liquid membrane. Dyes Pigments. 70 (2006) 99-104. DOI: https://doi.org/10.1016/j.dyepig.2005.05.002
G. Muthuraman, M. Sathya, M. Soniya, S. Elumalai. Recovery of Levafix brilliant red E-4BA and Levafix brilliant red E-6BA from aqueous solution by supported liquid membrane. Membr. Water. Treat. 4 (2013) 277-000. DOI: https://doi.org/10.12989/mwt.2013.4.4.277
P. Venkateswaran, K. Palanivelu. Studies on recovery of hexavalent chromium from plating wastewater by supported liquid membrane using tri-n-butyl phosphate as carrier. Hydrometallurgy. 78 (2005) 107–115. DOI: https://doi.org/10.1016/j.hydromet.2004.10.021